Nanopillar arrays have been employed in the study of field emission [1], solar cell industry [2], biological sensing [3], micro-/nanoscale fluidics, near-field optics, and the lab-on-a-chip technology [4]. Nanopore arrays have also been recognized as valuable structures in many advanced fields such as photovoltaic [5] and photonic crystal research [6], LY3023414 gas detection [7], and especially in biological molecules detection and separation [8]. Fitting with foregoing scientific
advancements, the nanoscale fabricating methods and technologies have been made good progress. Nanopillar and nanopore arrays can be fabricated with direct growth approaches (metal-organic chemical
vapor deposition, hydride vapor phase epitaxy, molecular beam epitaxy) [9–11], nanosphere-assist etching [12, 13], electronic beam lithography [14, 15], nanoimprint technology [16], and laser lithography [17]. Since the merits of fabricating speediness and cleanliness, maskless process, controllable pattern shape and size, and capability of lithograph in three https://www.selleckchem.com/products/pnd-1186-vs-4718.html dimensions [18, 19], laser direct lithography technology is one of the most attractive approaches to fabricate nanoscale functional structures as compared with the disadvantages such as expensive, heavy, or low precision of other methods. Choi’s group has reported implementing 100-nm-level nanostructure arrays over a large scale by means of laser interference lithography [20–23]. Scott and Li have respectively fabricated sub-100-nm isotropic voxel [24] and voxel with a 40-nm axial size [25] by photo-initiation
inhibiting technology. Cao has obtained a nanoline with a width of 130 nm and nanodots with a selleck diameter of 40 nm [26] by polymerization inhibiting, too. In Andrew’s work, the nanolines with an average width of 36 nm were drawn employing absorbance modulation lithography [27]. Tanaka and Thiel have shown fabricating spatial voxel to sub-120 nm with the two-photo-absorption technology [28, 29]. Qi got a single polymerized tip with a diameter of 120 nm with the same technical route [30]. However, the utilization of femtosecond laser systems makes the lithography system complex and Loperamide expensive. Even, in a continuous wave (CW) laser two-photon absorption method, photoresist is tailored and the whole system is costly. Furthermore, two laser sources are required in both photo-inhibiting and absorbance modulation methods, and the photoresist materials should have particular properties that result in restrictions in choosing light sources and resist materials. In the paper, we will report a kind of nanopillar array with a pillar diameter much smaller than Abbe’s diffraction limitation by visible CW laser direct lithography technology.